PW_(12)/g-C_3N_4光催化降解甲基橙

采用浸渍法制备了磷钨酸(PW12)/g-C3N4复合光催化剂,并将其用于溶液中甲基橙的光催化降解,运用IR技术对使用前后的光催化剂进行了表征。表征结果显示,PW12和g-C3N4的结构未在浸渍负载中发生改变,且PW12和g-C3N4结合牢固。实验结果表明:最佳的PW12负载量(光催化剂中PW12的质量分数)为50%;光催化降解甲基橙的优化反应条件为初始甲基橙质量浓度5 mg/L、光催化剂加入量0.6 g/L、初始溶液p H=7;在优化条件下,分别采用紫外光、模拟太阳光、可见光照射120 min后,甲基橙的降解率分别为96.59%,82.23%,42.78%;该光催化剂固载良好,使用中不易发生溶脱,稳定性好,可重复使用。     

The accounting method and application of CO2 emissions responsibility by the electricity sector at the provincial level in China

When accounting the CO₂ emissions responsibility of the electricity sector at the provincial level in China,it is of great significance to consider the scope of both producers’ and the consumers’ responsibility,since this will promote fairness in defining emission responsibility and enhance cooperation in emission reduction among provinces.This paper proposes a new method for calculating carbon emissions from the power sector at the provincial level based on the shared responsibility principle and taking into account interregional power exchange.This method can not only be used to account the emission responsibility shared by both the electricity production side and the consumption side,but it is also applicable for calculating the corresponding emission responsibility undertaken by those provinces with net electricity outflow and inflow.This method has been used to account for the carbon emissions responsibilities of the power sector at the provincial level in China since 2011.The empirical results indicate that compared with the production-based accounting method,the carbon emissions of major power-generation provinces in China calculated by the shared responsibility accounting method are reduced by at least 10%,but those of other power-consumption provinces are increased by 20% or more.Secondly,based on the principle of shared responsibility accounting,Inner Mongolia has the highest carbon emissions from the power sector while Hainan has the lowest.Thirdly,four provinces,including Inner Mongolia,Shanxi,Hubei and Anhui,have the highest carbon emissions from net electricity outflow- 14 million t in 2011,accounting for 74.42% of total carbon emissions from net electricity outflow in China.Six provinces,including Hebei,Beijing,Guangdong,Liaoning,Shandong,and Jiangsu,have the highest carbon emissions from net electricity inflow- 11 million t in 2011,accounting for 71.44% of total carbon emissions from net electricity inflow in China.Lastly,this paper has estimated the emission factors of electricity consumption at the provincial level,which can avoid repeated calculations when accounting the emission responsibility of power consumption terminals（e.g.construction,automobile manufacturing and other industries）.In addition,these emission factors can also be used to account the emission responsibilities of provincial power grids.     

中国服务业碳生产率的空间收敛性研究

在经济服务化与低碳化的双重背景下,研究中国服务业碳生产率的演变轨迹,区域差异及空间收敛特征,对于推动中国服务业高质量发展具有重要的意义。采用2004—2016年中国30个省(区、市)的面板数据,对服务业碳生产率进行测度,并对其演变轨迹与区域差异进行分析,在此基础上,系统考察中国服务业碳生产率的空间收敛性。研究表明:①中国服务业碳生产率在整体上呈逐年增长态势,且呈现从东到西逐次递减的格局。②中国服务业碳生产率存在正向空间自相关关系,并且空间自相关程度表现出波动上升趋势。③全国与西部服务业碳生产率均不存在σ收敛,即服务业碳生产率的地区差异并未随着时间的推移而缩小;东、中部服务业碳生产率则在整体上呈现σ收敛特征。全国以及东、中、西部服务业碳生产率均存在绝对β收敛和条件β收敛,即服务业碳生产率落后地区对发达地区存在"追赶效应",各地区服务业碳生产率最终向自身的稳态水平趋同;空间效应加快了全国与东部服务业碳生产率的β收敛速度。④人均服务业增加值增长速度、部门结构以及能源消费结构对服务业碳生产率具有显著的负向效应,人力资本则对服务业碳生产率产生了显著的正向影响。据此,本文的政策启示如下:①重视服务业碳排放问题,构建服务业低碳绩效评估体系。②探索建立定期会商制度,加强服务业低碳技术的跨区域交流合作。③完善基础设施,促进要素空间互动和优化重组。④调整服务业能源结构与部门结构,推进人力资本积累和服务业稳增长。     

瑞典生活垃圾处理方式及效果分析

生活垃圾分类回收管理措施正在我国各大城市全面实施。通过对瑞典生活垃圾层级管理和4种处理方式的介绍,对瑞典垃圾回收再利用效果进行分析,为我国推进生活垃圾分类回收再利用工作,提供可借鉴经验和参考。     

Forest resources and household welfare: Empirical evidence from North Central Vietnam

Using secondary data from a socio-economic quantitative household survey of the North Central region of Vietnam, the main aim of our study is to analyze the causal effect of forest resources on household income and poverty. Based on the observed characteristics of a forest-based livelihood and forest-related activities, we use a propensity score matching (PSM) method to control for potential bias arising from self-selection. The PSM results indicate that households with a forest-based livelihood had a higher level of income and lower poverty rates than did those without. Interestingly, our findings confirm that a forest-based livelihood offers much higher income than any other type of livelihood adopted by local households. Also, the poverty rate among households with a forest-based livelihood is lower than those earning non-labor income or engaged in wage/crop and crop livelihoods. Among households and provinces, we find varying opportunities deriving from forest resources, suggesting that there are potential barriers hindering local households from pursuing a forest livelihood or participating in some forest activities. Therefore, government policy and regulations on forest management should focus on improving the access of households to forest resources, while enhancing the sustainability of these resources.     

石墨相氮化碳协同UV-H_2O_2光催化降解亚甲基蓝

以三聚氰胺为前驱体,经热解—回流法制备了石墨相氮化碳(g-C3N4),采用XRD、FTIR、SEM、EDS、PL等技术对g-C_3N_4进行了表征。研究了g-C_3N_4在UV-H_2O_2体系中对废水中亚甲基蓝(MB)的光降解效果。实验结果表明,UV+g-C_3N_4催化剂+H_2O_2体系能协同降解MB,在初始MB质量浓度为20 mg/L、初始废水p H为5、废水体积为250 mL、g-C_3N_4加入量为0.10 g、H_2O_2浓度为0.4 mmol/L、反应温度为25℃的优化工艺条件下,紫外光照射70 min时MB脱色率达98.32%。g-C_3N_4催化剂具有较好的重复使用性能,使用5次后MB脱色率仍保持在95.10%。     

整合消费与增加值视角的中国行业碳排放变动分解研究

在研究影响我国CO 2排放因素领域,基于投入产出技术的分解模型已成为主要的分析工具,现有研究多分别基于消费视角或收益视角展开分析。为全面评估各行业收益与消费对其上游、下游行业碳排放的综合影响,整合基于收益与基于消费两个视角,运用2012年与2015年我国投入产出表,构建两层嵌套式结构分解分析模型(SDA),比较分析消费规模效应、收益规模效应、行业流入、流出增加值变动效应、增加值结构变动效应等14个影响各行业碳排放变动的关键因素,并借助对消费者原则碳排放估算公式的重构,更准确地实现从增加值视角对各行业消费者原则碳排放变动的关键影响因素分析。研究发现:①研究期内,我国在总产出增长29.14%的同时碳排放量上升1.46%,各行业碳排放强度下降是主要的减排因素,其中建筑业减排贡献最大。②增排效应方面,影响从大到小依次为消费规模、收益规模、完全投入结构与完全消费结构四项效应,且前两个规模效应的影响是后两个结构效应的2倍以上,尤其建筑业消费规模效应、煤炭采选产品业收益规模效应增排较大。③消费规模扩大导致增排的原因并非行业本身生产规模扩大,而主要在于建筑业、服务业等行业规模扩张时吸收其他行业流入的增加值量增多。④收益规模扩大导致的增排效应方面,细分来说从大到小依次为劳动者报酬、生产税净额、固定资产折旧、营业盈余四项效应,且行业差异显著,如煤炭采选产品业的劳动者报酬效应,石油、炼焦产品和核燃料加工品业的生产税净额效应以及电力、热力生产和供应业的营业盈余效应增排贡献较大,而煤炭采选产品业的营业盈余效应、批发、零售业和住宿、餐饮业的生产税净额效应则减排贡献较大。     

Effects of EGR on performance and emissions of a diesel engine fuelled with balanites aegyptiaca/diesel blends

In this study, balanites Aegyptiaca (L.) Del biodiesel was blended in proportions of 10% and 20% on the volume basis with diesel fuel and tested in a single cylinder, VCR diesel engine under measured load conditions with varied EGR rates (0, 10 and 20%). The results showed that B10 and B20 blends shown a significant reduction rate in terms of NO_x emissions that were familiar with biodiesel blends. At peak load conditions, BTE increased slightly for test fuel blends compared with pure diesel fuel while the BSFC rate and EGT suffered from increasing and decreasing nature with respect to blending percentage. From the emissions point of view, with the increase in blends percentage, a significant reduction rate is observed in terms of CO and HC concentrations (up to 12.34 and 17.5%, respectively) while NOx emissions decreased at peak load conditions (up to 24.34%). HC and CO emissions decreased with increase in blends percentage. However, lower levels of NO_x and EGT (up to 21.37 and 8.47%, respectively) and the average increase in terms of BTE and BSFC (up to 2.83 and 2.9%, respectively) can be realised with B20 test fuel blend under 20% EGR rate.     

自愿减排项目碳泄漏：内涵、类别及应对

自愿减排项目是碳排放交易市场抵消机制的运行载体,灵活的自愿减排抵消机制是碳排放交易市场的补充,对应对全球气候变化问题具有重要意义。碳泄漏,作为严重影响抵消项目减排效率的热点问题值得关注。目前,中国已形成较大规模的自愿减排市场,截至2018年底,国家发展改革委共签发了约7200万tCO_2当量减排量,我国在建立健全自愿减排抵消市场机制的过程中,需要把握项目碳泄漏的负外部性这一实质,厘清其运行机理并积极应对。本文旨在系统阐述该问题,并为进一步实现抵消项目减排潜力提供思路和方向:从自愿减排项目碳泄漏的内涵与定义出发,首先对项目碳泄漏的分类进行梳理,并依据产生途径的不同重点分析了活动转移排放、生命周期、市场路径、生态以及技术泄漏的作用机制、影响因素及其相应的研究方法;其次从具体项目应用、系统项目应用和宏观应用三个层面讨论了应对自愿减排项目碳泄漏问题的管理对策;最后结合我国自愿减排抵消市场的实际情况,建议未来抵消项目碳泄漏的应对和管理应在分门别类对其概念进行精准定义的基础上将解决措施的成本效益考虑在内,此外,在评估泄漏量时需要同时测算不同类型的碳泄漏,探究其协同效应以免高估其泄漏程度。     

大力推进城市资源循环利用基地建设——以北京市朝阳区资源循环利用产业基地为例

资源循环利用基地的建设是破解城市固体废弃物“邻避效应”的创新道路,有助于新型城市功能区的建设,是推进资源循环利用的主要方式。以北京市朝阳区资源循环利用产业基地为例,研究其基地建设的优势基础及制约因素,通过探索基地建设模式,分析了基地建设的总体思路和重要举措,以期为其他地区资源循环利用基地建设提供经验。